Gardening of the Martian Regolith by Diurnal CO2 Frost and the Formation of Slope Streaks L.Lange, Laboratoire de Météorologie Dynamique, Institut Pierre-Simon Laplace (LMD/IPSL), Sorbonne Université, Centre National de la Recherche Scientifique (CNRS), École Polytechnique, École Normale Supérieure (ENS), Paris, France (lucas.lange@lmd.ipsl.fr), S.Piqueux, Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA 91109, USA, C.S.Edwards, Northern Arizona University, Department of Astronomy and Planetary Science PO BOX 6010 Flagstaff, AZ 86011, USA. µm µm µm z = 10 µm 5 ~ ~ 32 µm 18 µm Fig 1. Schematic model of the CO2 frost (blue squares) and regolith dust grains (orange circles) relationship in dusty low thermal inertia regions, and its evolution throughout a night and sunrise. In this model, CO2 ice forms at depth, within the pores of the dusty surfaces. At sunrise, CO2 ice sublimates, creating an upward sublimation-driven wind that could lead to grain displacement. D 12 .5 z = 5 µm D Surface 5 ~ 10 Regolith Grain Movement m CO2 ice sublimation Approach: We use coincident visible and temperature observations acquired by THEMIS [10], a multispectral visible and thermal infrared wavelength imager. We only analyze data acquired near sunrise (i.e., 6 A.M. - 8 A.M), when adequate lighting allows the acquisition of multiband visible wavelength imagery of the ground. We only study infrared images coupled with visible wavelength images acquired simultaneously. Surface temperatures are derived from THEMIS band 9 centered at 12.57 µm as they offer the best signal on cold surfaces [10]. We eliminate image pairs clearly impacted by calibration issues (e.g., [11]) and poor observation conditions (mainly the identifiable presence of clouds in visible wavelength imagery). We identify the presence of ice on an image if the surface temperature retrieved is at the CO2 condensation temperature TCO2, within a margin of 5 K to account for instrumental noise. Once an image is flagged for CO2 ice, we inspect the associated visible wavelength image. The THEMIS visible camera has a resolution of 18 m/ pixel and has five filters with band centers located at 425 (band 1), 540 (band 2), 654 (band 3), 749 (band 4), and 860 nm (band 5) [10]. When available, we use « R2B » or « RGB » products available with the THEMIS public viewer: viewer.mars.asu.edu/viewer/ themis. 7µ 1 µm CO2 crystal 1 µm dust grain We proposed here to characterize the regolith/ice relationship in low thermal inertia terrains near equator through visible and infrared wavelength imagery analysis, surface features mapping, and numerical modeling. D Introduction: The seasonal transfer of CO2 between the atmosphere and the surface at high latitudes is associated with a wide range of exotic processes shaping the surface morphology [1 and references therein]. In contrast, the existence of a diurnal CO2 cycle at mid and low-latitudes has only recently been exposed [2,3]. [2,4] proposed that this diurnal CO2 cycle could impact the physical state of the regolith, preventing dust induration/duricrust formation, maintaining large mobile dust reservoirs, or the formation of geophysical features known as slopes streaks [5]. [2] suggests that diurnal frost in low thermal inertia terrains (i.e., dusty surfaces) should be present in the pores of the regolith, not exclusively on top of it (Fig. 1). With this regolith/ice interaction, the recurring diurnal growth and sublimation of CO2 crystals could indeed cryoturb the very surficial regolith. One consequence of this dirty frost model is that diurnal CO2 frost in low thermal inertia terrains should be excessively difficult to detect in visible wavelength imagery, in contrast with diurnal or seasonal CO2 frost present elsewhere on Mars forming on the top of the regolith grains. In addition, one potential implication for this recurring diurnal growth and sublimation of CO2 frost crystals within dusty terrain may include regular overnight surficial mechanical disruption of the soil, and possible fluffing by vertical sublimationdriven winds at sunrise. This process could maintain high regolith porosity, and prevent compaction or inter-grain induration/cementation that seems to be ubiquitous elsewhere on Mars [6,7] except in low thermal inertia terrains [8,9]. Probability Density of Photons Path Length Low Early Night Mid-Night Late Night Pre-Dawn Post-Sunrise High b a N 1 c N 2.5 f g Ls = 142.1° LTST = 7.43 1 42.8°S, 204.1°E 146 150 155 159 Tsurf [K] km 163 N 2 km km Ls = 132.1° LTST = 7.37 d 148 156 164 172 Tsurf [K] km 180 N 2 h Ls = 85.6° LTST = 7.03 i Ls = 126.1° LTST = 7.29 2 km 28.8°S, 43.3°E 150 158 165 173 Tsurf [K] 180 N 2.5 km km 2.5 41.2°S, 111.2°E e km j Ls = 13.9° LTST = 6.07 2 32.3°S, 133°E 147 160 173 186 Tsurf [K] km 199 2.5 26.5°N, 266°E 144 151 159 166 Tsurf [K] km 173 Fig. 2 Examples of THEMIS visible wavelength (a-e) and corresponding thermal infrared (f-j) images acquired simultaneously near dawn. The blue/white surface patches (a-d) and low surface temperatures within 5 K of TCO2 in infrared images (f-j). Coordinates, solar longitude (Ls), and local true solar time (LTST) are given in the different panels. Red arrows emphasize hard-to-distinguish blue/white patches. White arrow point to the position of the sun in the sky. a: Class 1, V71796004; b: Class 2, V63705007; c: Class 3, V78900003; d: Class 4, V63305007; e: Class 5, V76958011; f: I71796003 associated with a; g: I63705006 associated with b; h: I78900002 associated with c; i: I63305006 associated with d. j: I76958010 associated with e. f-j underlain with a THEMIS daytime IR mosaic to enhance topography [11]. Some terrains appear black in the thermal infrared images because of the background mosaic (not because of an absence of measurement) Surface frosts are identified based on their blue/ white hues, in stark contrast with the orange/brown/ grey surrounding terrains (Fig. 2). The vast majority of these blue/white units are confidently attributed to the surface (as opposed to the atmosphere) based on their sharp boundaries following morphometric or color units, topography, or preferential slope orientation. [2] demonstrated that CO2 diurnal frost should form thin layers (i.e., a few microns to tens of microns in thickness) of micrometer size ice crystals (as opposed to translucent slab-like ice) in dusty surfaces. Micrometer size CO2 ice crystals are associated with high albedo values at visible wavelengths [12], but dust contamination can drastically reduce it. [13] showed however that micrometer size ice crystals forming the top of dusty surfaces can be detected in these dusty surfaces. Hence, the albedo (or color) of frosted terrains provides an excellent diagnostic tool of the relationship between the ice and the regolith grains. Furthermore, the surface emissivity is highly sensitive to the presence of frost on the surface at λ ~ 12.57 µm (THEMIS band 9, [10]), even for thin frost layer. We therefore also use the surface emissivity to further constrain the frost/ regolith relationship in the low thermal inertia regions of Mars. Results: THEMIS surface temperatures acquired at sunrise are consistent with the presence of CO2 frost at virtually all latitudes (black and white dots in Fig. 3), confirming results presented by others with MCS [2] and THEMIS [3]. We find that 848 image pairs (out of 2,761, i.e. ,~30%, that have been flagged for CO2 ice) that do not show a signature of frost in visible wavelength imagery, while the ground is at CO2 ice temperature. Noticeably, no identification in visible wavelength imagery is located in the 45°N-15°S latitude band in the low thermal inertia terrains (i.e., purple in Fig.3,), where widespread diurnal CO2 frost forms during a significant fraction of the year [2]. In contrast, at other latitudes, 87.5% of the image pairs at the CO2 frost point temperature are associated with bright patches on the ground (whether contaminated by water ice or not). Most of the missing frost signatures in visible wavelength imagery when the surface temperatures at TCO2 at high latitudes are generally linked to poor image quality, with challenging illumination conditions that prevent us from clearly assessing the color of the surface. This 90 T12 ~ TCO2 No blue surfaces T12 ~ TCO2 With blue surfaces 60 25 125 325 225 400+ Latitude 30 0 -30 -60 -90 0 45 90 135 180 225 270 315 360 Fig. 3 Distribution of dawn THEMIS visible and infrared wavelength image pairs within 5 K of the local CO2 frost point. Black dots indicate no signature of frost in visible wavelength images (848 images). White dots indicate the presence of image pairs where frost is identified at visible wavelengths (1,931 cases). Colorized background is a thermal inertia map overlaid on with a MOLA shaded relief only shown outside the maximum extent of the continuous seasonal caps. During the winter, the Northern high/mid latitudes are subject to much fewer observations than the Southern high/mid latitudes, partially explaining the hemispheric asymmetry Longitude (East) difference suggests that on low thermal inertia terrains, the visible wavelength optical properties of diurnal frost are uniquely dominated by those of the surface dust, i.e., ice forms within the pores the dusty layer. The observations are thus consistent with dirty diurnal CO2 ice in these terrains, following the hypothesis formulated by [2] , and illustrated in Fig.1. Discussions: Based on Earth analogies [14,15], we assume We acknowledge that a regolith/ice relationship that the recurring growth and removal of ice may diagnosis solely based on terrain color can be comcreate a stress cycle in the regolith leading to internal plicated by the lowering of the ice's albedo by dust grain displacement and microscopic weathering. At (e.g., [12]). Fig. 4 shows that most of THEMIS imsunrise, the rapid sublimation of the diurnal ice creages in dusty grounds display a high surface emissivates a short-lived wind field within the regolith that ity, close to the emissivity of ice-free dusty grounds exerts a drag on individual grains, that could pro(0.96 [2]). We find that more than 70% of the immote the displacement of the dust grains. [13] comages show a CO2 frosted surface emissivity between putations show that frost sublimation-driven wind at 0.96 ± 0.04 (uncertainty defined as the 3-σ spread sunrise reaches up to 3.2 cm s-1, with a mean value from our 5 K tolerance). Such high emissivities at between 1.5 and 2.0 cm s-1 (standard deviation of 0.8 12.57 µm suggest the absence of CO2 frost over cm s-1 as a function of season, latitude, and elevation. dusty surfaces, or over micrometer size thickness These values are upper limits and are generally larg(Fig. 11 in [2]). But in the latter case the ice thicker than (but comparable to) other values reported in nesses would be inconsistent with mass/energy balthe literature for seasonal ice sublimation and Knudance results [2]. Thus, the high surface emissivity sen pumping [16,17]. Using a simple 1-D balance values are most consistent with an absence of frost model, we show that [13] the vertical drag exerted on the surface. on individual grains can be larger and opposite in direction to cohesion plus gravity forces, suggesting Thermal Inertia [J m K s ] that motion can be initiated by this wind. Local b 70 slope, and more importantly grain packing angle as THEMIS emissivity with T ⩽ T well as cohesion forces between grains are important Dust Emissivity factors controlling whether grain motion can occur. 60 Surface Emissivity of 10 µm CO Frost + Dust Surface Emissivity of 100 µm CO Frost + Dust Winds faster than 2.5 cm s-1 are occasionally encountered and should be able to disrupt the ground on 50 most sloped and poorly cohesive low thermal inertia terrains; Consequently, this grain-displacement induced 40 by CO2 sublimation could promote other dynamic phenomena as slope streaks. Slopes streaks are dark 30 wedge-shaped surface features on sloped dusty terrains, associated with mass movement downslope [18]. The formation process for slope streaks is still 20 debated, and generally falls into two categories: wet vs. dry mechanisms, although both types can be associated with dust avalanches. [19]. These slope 10 streaks are observed where diurnal dirty frost is expected most of the year [13]. We therefore assume 0 that at sunrise, this diurnal frost sublimates, initiat0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 Number of image pairs ing a vertical drag on individual grains able to set Mean Emissivity ε those uncohesive in motion . In this model, steep Fig. 4 CO2 emissivity derived at λ = 12.57 µm. Dust emissivity dusty terrains already close to the angle of repose at 12.57 µm (red line) from [2]. Modeled emissivity of the dusty surface overlaid by 10 µm (solid line) and 100 µm (dashed line) CO2 ice layer indicated in blue [2]. Number of image pairs a -2 CO 2 2 Mean Emissivity Number of image pairs 2 -1 -1/2 (i.e., 30-35° [20]) are destabilized and initiate an avalanche of dust. Our results also show that the velocities reached during sublimation can be high enough to exceed the velocity threshold computed in [21] required for fluidization of avalanching material. These fluidization of the avalanching material is necessary to explain the length and width of the slope streaks given. We hypothesize that diurnal CO2 ice sublimation may be triggering and sustaining the growth of slope streaks, but other factors such as local winds may be involved in this process. Our proposed model overcomes several limitations of competing dry mechanisms presented in the literature, but it is not unequivocally validated by observations constraining the seasonality or orientation of slopes highlighted by others. Conclusions: We have conducted an analysis of THEMIS visible and thermal infrared data acquired at dawn. This work constrains the relationship between diurnal frost and the surficial regolith on Mars. It unveils the potential geomorphological impact of the diurnal CO2 cycle. Specifically: • The distribution of THEMIS thermal infrared data acquired at dawn confirms the widespread nature of CO2 frost on Mars previously reported [2,3]; • Multiband THEMIS visible wavelength images acquired at dawn frequently show blue/white hues interpreted as clean surface frost over a significant fraction of the surface. However, In the mid-to-low latitude low thermal inertia terrains (45°N-15°S), surface temperatures consistent with the presence of CO2 frost on the ground do not show any frost signature in visible wavelength imagery, suggesting the formation of dirty frost. • This conclusion is also supported by the high emissivity at 12.57 µm of these frosted surfaces; • Recurring regolith grain movement on Mars instigated by overnight CO2 crystal growth and rapid sublimation at sunrise could prevent the induration of the regolith observed elsewhere, maintaining large surface dust reservoirs available for lifting in the atmosphere; • Within the regolith, wind generated by the sublimation of CO2 ice could exert a drag on the dust grains, promoting the displacement of these grains; • This displacement induced by the sublimation of diurnal frost could trigger the formation of slope streaks, especially since wind velocities required for fluidization are met. The sublimation of CO2 frost after dawn may not be the only necessary factor required for their formation • This potential CO2 sublimation-driven geomorphological activity show that CO2 is a geomorphological agent on all of the surface of Mars, not only in the polar latitudes. Acknowledgements: Part of this work was performed at the Jet Propulsion Laboratory, California Institute of Technology, under a contract with NASA. US government acknowledged. References: [1] Diniega et al. (2021), 10.1016/j.geomorph. 2021.107627 [2] Piqueux et al. (2016), 10.1002/2016je005034 [3] Khuller et al. (2021), 10.1029/2020JE006577 [4] Mischna & Piqueux (2020), 10.1016/j.icarus. 2019.113496 [5] Schorgoffer et al. (2007), 10.1016/j.icarus. 2007.04.026 [6] Jakosky & Christensen (1986), 10.1029/ jb091ib03p03547 [7] Mellon et al. (2000), 10.1006/icar.2000.6503 [8] Piqueux & Christensen (2009), 10.1029/2008je003308, 10.1029/2008je003309 [9] Putzig et al. 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