NOMAD ON EXOMARS TRACE GAS ORBITER: OBSERVATIONS, CALIBRATION, AND PUBLICLY AVAILABLE DATA I. R. Thomas, L. Trompet, Y. Willame, A. Piccialli, J. T. Erwin, A.C. Vandaele, B. Ristic, S. Robert, Z. Flimon, F. Vanhellemont, F. Daerden, L. Neary, S. Viscardy, C. Depiesse, Royal Belgian Institute for Space Aeronomy (BIRA-IASB), Brussels, Belgium (ian.thomas@aeronomie.be), S. Aoki, University of Tokyo, Tokyo, Japan, M.R. Patel, Open University, Milton Keynes, U.K., and STFC Rutherford Appleton Laboratory, Oxfordshire U.K, J.J. Lopez Moreno, Instituto de Astrofisica de Andalucia (IAA/CSIC), Granada, Spain, G. Bellucci, Istituto di Astrofisica e Planetologia Spaziali (IAPS/INAF), Rome, Italy, and the NOMAD Team Introduction: NOMAD is a suite of three spectrometers onboard the ExoMars 2016 Trace Gas Orbiter, designed to measure the constituents of the Martian atmosphere in unprecedented detail [1]. The three channels observe gas species in the 200-650 nm and 2.2-4.3 µm spectral regions, in nadir, limb and solar occultation modes [2]. NOMAD has been operating continuously since April 2016 and has already generated a wealth of data about the atmospheric constituents and processes on Mars. LNO also observes the nightside of the planet occasionally, plus the Mars’ limb on both the dayside and nightside to search for non-LTE CO2 emissions. Recently, observations have been made of Phobos and Deimos: Phobos is certainly observable by LNO; however Deimos is potentially too small and too distant from TGO to be observed. Optimisation of these observations is ongoing: systematic noise removal, FOV pointing direction and the trade-off between the SNR and the number of spectral regions measured are all under investigation. Observations: SO channel: Typically, the SO channel operates in the infrared in solar occultation mode, measuring six spectral regions ~30 cm-1 wide at a resolution of ~0.15 cm-1 in each occultation [3]. The spectral regions are chosen based on the desired molecules/atmospheric constituents, isotopologues and altitude ranges, where the lines are strong enough to be observable but not saturated. The channel can also operate in ‘fullscan’ mode, where any number of spectral regions are measured consecutively, covering the full spectral range of the channel or a selected region, for example [4]. Absorption lines of H2O [5], CO [6], CO2 [7] and their isotopologues, plus aerosols [8], are measured in almost every occultation, with searches for HCl [9], CH4 [10] and other trace gases and clouds made regularly. UVIS channel: This channel operates in the same modes as SO and LNO, measuring solar occultations, dayside + nightside nadirs and dayside + nightside limbs, in the ultraviolet and visible spectral region from 200-650 nm. Unlike SO and LNO, the full spectral range is typically measured on every observation, with a spectral resolution of ~1.5 nm [14] when operating in unbinned mode for nadirs and limbs. For solar occultations, spectral binning is normally performed, giving a spectral resolution of ~12nm [14]. In solar occultation and nadir modes, the channel observes O3 [15] and dust/aerosols [16]. In limbpointing mode, airglow is observed: the green [17] and red [18] lines have both been measured and we are currently searching for auroral emissions in the nightside limb observations. The UVIS channel has also successfully observed Phobos and Deimos; calibration and observation optimisation of these observations is ongoing. LNO channel: This channel measures primarily in nadir, measuring 2-6 spectral regions ~30 cm-1 wide at a resolution of ~0.2 cm-1 [3] in each nadir pass over the dayside of Mars when operating. The spectral range is limited to 2.2-3.8 µm [1] and it typically observes in nadir on one-out-of-four orbits for thermal and lifetime considerations. Absorption lines of H2O [11] and CO [12] are measured in almost every nadir observation, with searches for HDO and CH4 made regularly. The channel occasionally operates in ‘fullscan’ mode, to probe a wider spectral range in nadir mode; the channel can also operate in solar occultation mode and has made some fullscans during solar occultations like the SO channel [13]. Calibration: Recently, several calibration papers have been published for all three channels:  Calibration of NOMAD on ESA′s ExoMars Trace Gas Orbiter: Part 1 – The Solar Occultation channel [4]  Calibration of NOMAD on ESA′s ExoMars Trace Gas Orbiter: Part 2 – The Limb, Nadir and Occultation (LNO) channel [13]  Calibration of NOMAD on ExoMars Trace Gas Orbiter: Part 3 - LNO validation and instrument stability [19]  Calibration of the NOMAD-UVIS data [14]  Removal of straylight from ExoMars NOMADUVIS observations [20]  The deuterium isotopic ratio of water released from the Martian caps as measured with TGO/NOMAD (supporting information) [21] These papers describe in detail the latest calibration analysis, giving data users insight into how the instrument was calibrated and important information for understanding how NOMAD’s three channels function for further analysis of the spectra. Availability of Data: At the time of writing (April 2022), work is ongoing to convert almost all NOMAD data into the NASA PDS4 format [22]. This data will then be available to everyone via the ESA PSA interface [23]. The observations that will be available are as follows:  SO + UVIS occultations (figure 1)  SO + LNO occultation fullscans (figure 2-3)  LNO + UVIS day nadir (figure 4)  UVIS night nadir  UVIS day limb (figure 5)  UVIS night limb The other remaining observation modes (LNO night nadirs; LNO day + night limbs; LNO day nadir fullscans and LNO + UVIS Phobos/Deimos) will be delivered to the PSA when the respective calibrations are ready. Each observation on the PSA has an associated thumbnail image: examples of these can be found in figures 1-5. References: [1] Vandaele, Ann Carine, et al. "Science objectives and performances of NOMAD, a spectrometer suite for the ExoMars TGO mission." Planetary and Space Science 119 (2015): 233-249. https://doi.org/10.1016/j.pss.2015.10.003 [2] Robert, S., et al. "Expected performances of the NOMAD/ExoMars instrument." Planetary and Space Science 124 (2016): 94-104. https://doi.org/10.1016/j.pss.2016.03.003 [3] Liuzzi, Giuliano, et al. "Methane on Mars: New insights into the sensitivity of CH4 with the NOMAD/ExoMars spectrometer through its first in-flight calibration." Icarus 321 (2019): 671-690. https://doi.org/10.1016/j.icarus.2018.09.021 [4] Thomas, Ian R., et al. "Calibration of NOMAD on ESA's ExoMars Trace Gas Orbiter: Part 1–The Solar Occultation channel." Planetary and Space Science (2021): 105411. https://doi.org/10.1016/j.pss.2021.105411 [5] Aoki, Shohei, et al. "Water vapor vertical profiles on Mars in dust storms observed by TGO/NOMAD." Journal of Geophysical Re- search: Planets 124.12 (2019): 3482-3497. https://doi.org/10.1029/2019JE006109 [6] Yoshida, Nao et al. "Variations in vertical CO/CO2 profiles in the Martian mesosphere and lower thermosphere measured by the ExoMars TGO/NOMAD: Implications of variations in eddy diffusion coefficient", submitted to Geophysical Research Letters [7] Trompet, Loïc, et al., “Carbon dioxide retrievals from NOMAD-SO on ESA’s ExoMars Trace Gas Orbiter and temperature profiles retrievals with the hydrostatic equilibrium equation. II. Temperature variabilities in the mesosphere at Mars terminator.”, submitted to Journal of Geophysical Research: Planets. [8] Liuzzi, Giuliano, et al. "First detection and thermal characterization of terminator CO2 ice clouds with ExoMars/NOMAD." Geophysical Research Letters 48.22 (2021): e2021GL095895. https://doi.org/10.1029/2021GL095895 [9] Korablev, Oleg, et al. "Transient HCl in the atmosphere of Mars." Science Advances 7.7 (2021): eabe4386. https://doi.org/10.1126/sciadv.abe4386 [10] Knutsen, Elise W., et al. "Comprehensive investigation of Mars methane and organics with ExoMars/NOMAD." Icarus 357 (2021): 114266. https://doi.org/10.1016/j.icarus.2020.114266 [11] Crismani, M. M. J., et al. "A global and seasonal perspective of Martian water vapor from ExoMars/NOMAD." Journal of Geophysical Research: Planets 126.11 (2021): e2021JE006878. https://doi.org/10.1029/2021JE006878 [12] Smith, Michael D., et al. "The climatology of carbon monoxide on Mars as observed by NOMAD nadir-geometry observations." Icarus 362 (2021): 114404. https://doi.org/10.1016/j.icarus.2021.114404 [13] Thomas, Ian R., et al. "Calibration of NOMAD on ESA's ExoMars Trace Gas Orbiter: Part 2–The Limb, Nadir and Occultation (LNO) channel." Planetary and Space Science (2021): 105410. https://doi.org/10.1016/j.pss.2021.105410 [14] Willame, Yannick, et al. “Calibration of the NOMAD-UVIS data”, submitted to Planetary and Space Science. [15] Patel, M. R., et al. "ExoMars TGO/NOMAD‐ UVIS Vertical Profiles of Ozone: 1. Seasonal Variation and Comparison to Water." Journal of Geophysical Research: Planets 126.11 (2021): e2021JE006837. https://doi.org/10.1029/2021JE006837 [16] Streeter, P., et al. “Vertical aerosol distribution and mesospheric clouds from ExoMars UVIS”, submitted to Journal of Geophysical Research: Planets. [17] Gérard, J-C., et al. "Detection of green line emission in the dayside atmosphere of Mars from NOMAD-TGO observations." Nature Astronomy 4.11 (2020): 1049-1052. https://doi.org/10.1038/s41550-020-1123-2 [18] Gérard, J‐ C., et al. "First observation of the oxygen 630 nm emission in the Martian dayglow." Geophysical Research Letters 48.8 (2021): e2020GL092334. https://doi.org/10.1029/2020GL092334 [19] Cruz Mermy, G., et al. "Calibration of NOMAD on ExoMars Trace Gas Orbiter: Part 3-LNO validation and instrument stability." Planetary and Space Science (2021): 105399. https://doi.org/10.1016/j.pss.2021.105399 [20] Mason, Jonathon P., et al. "Removal of straylight from ExoMars NOMAD-UVIS observations." Planetary and Space Science (2022): 105432. https://doi.org/10.1016/j.pss.2022.105432 [21] Villanueva, Geronimo, et al. “The deuterium isotopic ratio of water released from the Martian caps as measured with TGO/NOMAD”, submitted to Journal of Geophysical Research: Planets [22] https://pds.nasa.gov/ [23] Besse, S., et al. "ESA's Planetary Science Archive: Preserve and present reliable scientific data sets." Planetary and Space Science 150 (2018): 131-140. https://doi.org/10.1016/j.pss.2017.07.013 Figure 1: SO (left) and UVIS (right) solar occultation spectra. Thumbnail images available on the ESA PSA. Figure 2: SO solar occultation fullscan spectra. Thumbnail images available on the ESA PSA. Figure 3: LNO solar occultation fullscan spectra. Thumbnail images available on the ESA PSA. Figure 4: LNO (left) and UVIS (right) day nadir spectra. Thumbnail images available on the ESA PSA. Figure 5: UVIS day limb altitude profile and spectra. Thumbnail images available on the ESA PSA.